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  7. Free Energies of Polyatomic Polarizable Dipole‐Active Particles in Polar Media
 
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Free Energies of Polyatomic Polarizable Dipole‐Active Particles in Polar Media

Journal
physica status solidi (b)
ISSN
0370-1972
1521-3951
Date Issued
1989-07
Author(s)
Marsagishvili, Tamazi  
Rafael Agladze Institute of Inorganic Chemistry and Electrochemistry  
Matchavariani, Marine  
Rafael Agladze Institute of Inorganic Chemistry and Electrochemistry  
Publisher
Wiley
DOI
10.1002/pssb.2221540108
URI
https://onlinelibrary.wiley.com/doi/abs/10.1002/pssb.2221540108
https://openscience.ge/handle/1/8426
Abstract
A calculation method is given of free energy change of polyatomic polarizable dipole-active particles at their dissolution in inhomogeneous polar media. Two mechanisms of interaction between the particles and polar media are considered: solvatational and fluctuational mechanisms including ion–dipole and dipole–dipole interactions. Received analytical expressions permit to carry out the calculations for the dissoluted particles with any finite number of intramolecular degrees of freedom, taking into account the spatial and frequency dispersion of media.
Subjects

polar systems

dipole particles

charge transfer

free energy

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